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Rare-earth doped chalcogenide glass laser

T.Schweizer, D.W.Hewak, D.N.Payne, T.Jensen* and G.Huber*
*Institut für Laser-Physik, Universität Hamburg, Jungiusstraβe 9a, 20355 Hamburg, Germany

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Abstract

Laser action in a rare-earth doped chalcogenide glass was demonstrated for the first time showing that this class of glasses is suitable for active applications such as optical amplifiers and lasers. The neodymium-doped gallium lanthanum sulphide glass laser operated continuous wave at a wavelength of 1.08 μm when pumped with a Ti:sapphire laser at either 0.815 μm or 0.890 μm.

Introduction
The family of the chalcogenide glasses has been studied extensively due to their interesting optical, electrical and acoustic properties [1]. The main optical features of chalcogenide glasses compared to the common silica glasses are their transparency at long wavelengths and their low non-radiative decay rates of rare-earth energy levels both of which result from the low vibrational frequencies of the glass bonds. Together with an increase in the radiative decay rate of these energy levels due to the high refractive index of the chalcogenides, these glass properties open up new transitions and increase the quantum efficiency of existing transitions between rare-earth energy levels compared to silica and fluoride glasses [2-4]. However, to our knowledge, laser action in rare-earth doped chalcogenide glasses has not been demonstrated to date.

Neodymium-doped gallium lanthanum sulphide glass (Ga:La:S) was proposed as a laser material earlier by Bornstein et al. and Flahaut et al. [5, 6]. Calculations of the laser threshold for side-pumping showed a lower value for Ga:La:S glass than for other glasses and YAG crystals, however laser action could not be achieved.

In this paper we present spectroscopy and the first laser experiments on neodymium-doped Ga:La:S glass.

Experiments and results
A Nd3+-doped Ga:La:S glass was prepared by mixing Ga2S3, La2S3, and Nd2S3 powders with the molar ratio of 70:28.5:1.5, melting at 1150°C for eight hours, and quenching the melt to room temperature.

Absorption measurements in the visible and near-infrared spectral region were performed with an Perkin Elmer Lambda 9 spectrophotometer. The mid-infrared absorption was measured with a Fourier Transform Spectrometer (Perkin Elmer System 2000 FT-IR). Figure 1 shows the ground state absorption spectrum of a 1.42 mm thick sample in the whole spectral range. The spectrum shows the wide transmission range of the glass starting at the UV absorption edge at 0.5 μm and extending beyond 8 μm. This allows the measurement of the absorption into the 4I11/2 level at 5.2 μm. The absorption bands of the 2H9/2 and 4F5/2 levels and the upper laser level 4F3/2 at 0.815 μm and 0.890 μm, respectively, were used to pump the 4F3/24I11/2 laser transition. The absorption coefficient of the 2H9/2 and 4F5/2 levels is three times larger than the absorption coefficient of the 4F3/2 level leading to absorption lengths of 0.7 mm and 2.0 mm, respectively.


Figure 1. Room temperature ground state absorption spectrum of 1.42 mm thick 1.5mol% Nd-doped Ga:La:S glass with reciprocal wavelength scale

For fluorescence measurements the Nd3+-ions were excited into the 2H9/2, 4F5/2 levels using a Ti:sapphire laser operating at 0.815 μm. Multiphonon decay from the 2H9/2, 4F5/2 levels populates the 4F3/2 level which has a decay time of 70 μs. Three fluorescence transitions have been measured with an ANDO spectrum analyser. They are shown in figure 2 together with the pump laser spectrum. Laser action on each of these transitions has been reported in many host materials. In this work laser operation could only be obtained on the strongest transition at 1.08 μm.


Figure 2. Room temperature fluorescence spectrum of Nd-doped Ga:La:S glass

A simple hemispherical resonator consisting of a plane input coupler having high reflectivity at 1.08 μm and various output couplers with 50 mm radius of curvature were used for the laser experiments. The glass sample was placed close to the plane input mirror. A 50 mm focal length lens focused the Ti:sapphire pump beam into the glass sample. The output power was measured with a pyroelectric powermeter using suitable filters to block the unabsorbed Ti:sapphire radiation.

Laser action could be achieved with a 1.42 mm thick sample of Ga:La:S glass doped with 1.5mol% (2.6×1020 ions/cm3) neodymium for pump wavelengths of 0.815 μm and 0.890 μm. The laser spectrum extended from 1.073 μm to 1.087 μm with a maximum at 1.08 μm. Better laser results could be obtained with the longer pump wavelength that directly excites the upper laser level without generating heat through the multiphonon decay from the 2H9/2, 4F5/2 levels to the upper laser level 4F3/2. The smaller absorption coefficient at 0.890 μm also reduces the thermal load on the glass and leads to a more homogeneous excitation of the sample. At a pump wavelength of 0.815 μm 88% of the pump power is absorbed while at a pump wavelength of 0.890 μm only 50% is absorbed. The dependence of the output power on the absorbed pump power in figure 3 clearly shows the thermal problems of the glass. Laser action ceases at high pump powers.


Figure 3. Output power versus absorbed pump power of the 1.08 μm Nd-doped Ga:La:S glass laser pumped at 0.890 μm for values of output coupling (oc) and slope efficiency (η)

These problems are expected due to the high coefficient of thermal expansion and the strong change of the refractive index with temperature dn/dT in chalcogenide glasses [1]. The two effects lead to strong thermal lensing that was observed directly by superimposing a red He/Ne laser beam on the infrared Ti:sapphire beam. When the Ti:sapphire was tuned to a neodymium absorption band the glass acted as a strong lens for the red He/Ne laser beam. The two input-output curves with 1% and 5% output coupling, respectively, show a minimum threshold of less than 10 mW, a maximum output power of 2.7 mW and a maximum slope efficiency η of 11%. The slope efficiency was fitted to the linear part at the beginning of each curve. Laser action could be achieved with an output coupling of up to 10%.

Conclusion
In conclusion we have demonstrated the first rare-earth doped chalcogenide glass laser. A Nd-doped Ga:La:S glass showed cw laser action at room temperature at a wavelength of 1.08 μm. The reasonably low laser threshold indicates acceptable glass losses but this preliminary laser performance is worse in comparison with conventional Nd-lasers. Improvements will be made by optimizing the doping concentration and the length of the sample. The results are a first step towards the realisation of fibre lasers operating at new wavelengths and 1.3 μm amplifiers for telecommunication based on Ga:La:S glass fibres, progress is also supported by recent results in Ga:La:S glass fibre fabrication [7].

Acknowledgments
Chalcogenide starting materials were supplied by Merck Ltd. Thanks to Roger Moore for help with the glass fabrication.

References

1. P N Kumta and S H Risbud, 'Review: Rare-earth chalcogenides - an emerging class of optical materials', J. Mater. Sci., 1994, 29, pp. 1135-1158

2. J Heo, 'Optical characteristics of rare-earth-doped sulphide glasses', J. Mater. Sci. Lett., 1995, 14, pp. 1014-1016
3. B G Aitken, C W Ponader and M A Newhouse, 'EPR spectroscopy and fluorescence of rare-earth-doped GeAs sulphide glasses', VIII Int. Conf. Physics Non-Cryst. Solids, 1995, Turku, Finland, Abstracts, p. 35
4. P C Becker, M M Broer, V G Lambrecht, A J Bruce and G Nykolak, 'Pr3+:La-Ga-S glass: A promising material for 1.3 µm fibre amplification', in Proc. OSA Top. Meet. Opt. Amplifiers Appl., Santa Fee, NM, June 1992, postdeadline paper PD5, pp. 20-23
5. A Bornstein and R Reisfeld, 'Laser emission cross-section and threshold power for laser operation at 1077 nm and 1370 nm; chalcogenide mini-lasers doped by Nd3+', J. Non-Cryst. Solids, 1982, 50, pp. 23-27
6. J Flahaut, M Guittard, and A M Loireau-Lozac 'h, 'Rare earth sulphide and oxysulphide glasses', Glass Technology, 1983, 24, pp. 149-156
7. D W Hewak, R C Moore, T Schweizer, J Wang, B Samson, W S Brocklesby, D N Payne, and E J Tarbox 'Gallium lanthanum sulphide fibre for active and passive applications', accepted for publication in Electron. Lett.


Electronics Letters (1996) Vol.32(7) pp.666-667

doi: 10.1049/el:19960430

Southampton ePrint id: 78081

 

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Copyright University of Southampton 2006